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Extra info for Integrated Design of Alternative Technologies for Bulk-Only Chemical Agent Disposal Facilities (Compass Series (Washington, D.C.).)

Example text

High-pressure oxygen was used as the oxidant. Coupons of various materials were attached to a coupon tree placed along the reactor length. In this way, coupons could be placed in different regions of the reactor along its length, including a quench zone at the end of the reactor. The coupons were subsequently examined under a microscope to determine microstructural effects and thicknesses as a function of location in the SCWO reactor. The following materials were tested: • noble metals (platinum, Pt-20%Ir, Pt-10%Rh), Au-8%Pd, Rh) • platinum-plated metals, ceramics (magnesium-stabilized zirconia [MSZ], YSZ) • nickel-steel alloys (C276, I617, I625, I690, HA25, HA188) • refractory tantalum and niobium (for quench zone and downstream components only) The preliminary results of the tests are shown in Table 3-1.

Process water is received from the plant water supply and is stored in the Process Water Tank. 4 Reagent Storage and Preparation Module (One Unit) The Reagent Storage and Preparation Module heats process water for use in the TCC and Neutralization Modules, stores sodium hydroxide for use in the neutralization reaction, and dilutes and stores sodium hydroxide for decontamination uses. Cold process water is received from the Water Storage Module. Eighteen percent sodium hydroxide is delivered by truck and stored undiluted for use in the neutralization reaction.

VOC removal from hydrolysate at the ABCDF) will also have to be disposed of. This carbon is intended to be regenerated and reused. Process monitoring, record keeping, and segregation will be necessary to differentiate the carbon that is or has potentially been exposed to agent from that which has not. Carbon exposed (or potentially exposed) to agent is not being considered for regeneration, whereas unexposed carbon is expected to be regenerated. Activated carbon that has been used to treat exhaust from areas known to be contaminated or areas that could potentially be contaminated with agent will have to be shown to be free of agent to below required levels for shipment off site.

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