By Yury Gogotsi and Volker Presser
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Extra info for Carbon Nanomaterials
The nanoribbons produced by this method are typically 15–40 nm wide and 100–500 nm long. 9 (a) Pristine MWCNT, (b) MWCNT coated with a PMMA film, (c) the PMMA–MWCNT film was peeled from the substrate, turned over, and exposed to an Ar plasma etching, (d–g) possible products generated by controlling the etching time. Y. ) 18 Carbon Nanomaterials e. Electrical method. 113 found that MWCNTs could be easily unwrapped to form GNRs. By using movable electrodes and controlling the voltage bias, the outer wall of MWCNT is severed to form GNR attached to the remaining inner core.
Similarly, Subramanyam99 reported the fabrication of crystalline carbon nanoribbons by pyrolysis of ferrocene and tetrahydrofuran (THF). 2 Nanocutting Contrary to the CVD process, nanocutting of graphene is a versatile and efficient method for the fabrication of GNRs. 101 By means of catalytic hydrogenation, catalytic nanocutting of graphene has been reported using nickel or iron nanoparticles in the presence of hydrogen at high temperatures. Datta et al. 102 Using the single-particle etching technique, GNR with width of 15 nm and lengths on the order of micrometers was fabricated.
C. , Science, 323, 610, 2009. ) (b) Scanning tunneling microscopy image of hydrogenated graphene and four different types of hydrogen on the surface of graphene. (With permission from Balog, R. , J. Am. Chem. , 131, 8744, Copyright 2009. ) (c) STM image shows the graphene pattern with changes as a function of the positive sample bias. (d) The patterned institutional logo and initials by STM tips. (From Sessi, P. , 9, 4343, 2009. 22 (a) Structure of graphene. (b) Structure of fluorographene. , ACS Appl.
Carbon Nanomaterials by Yury Gogotsi and Volker Presser