By Wolfgang Demtröder
This advent to Atomic and Molecular Physics explains how our current version of atoms and molecules has been built over the past centuries through many experimental discoveries and from the theoretical part via the advent of quantum physics to the enough description of micro-particles.
It illustrates the wave version of debris via many examples and exhibits the bounds of classical description. The interplay of electromagnetic radiation with atoms and molecules and its strength for spectroscopy is printed in additional element and specifically lasers as smooth spectroscopic instruments are mentioned extra thoroughly.
Many examples and issues of suggestions should still result in the reader to an severe energetic cooperation.
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Gusarova, A. V. Artem’ev, S. F. Malysheva, N. A. Belogorlova, A. O. Korocheva, O. N. Kazheva, G. G. Alexandrov and O. A. , 2012, 22, 187. B. A. Trofimov, N. K. Gusarova, A. V. Artem’ev, S. F. Malysheva, N. A. Belogorlova and A. O. , 2012, 23, 411. K. Izod, J. M. Watson, W. Clegg and R. W. Harrington, Eur. J. Inorg. , 2012, 1696. ¨rls, S. Krieck and M. Westerhausen, T. M. A. Al-Shboul, G. Volland, H. Go Inorg. , 2012, 51, 7903. K. Izod, Coord. Chem. , 2012, 256, 2972. ¨tter, M. Eberl, G. Bala ´zs, M.
356 The newly prepared sterically-crowded diphosphine (104) has been shown to undergo homolytic P–P bond cleavage to form two phosphinyl radicals. , 2014, 43, 1–51 View Online 357 insertion of elements into the P–P bond. 360 N X P P X R R* N R* N N N R* N R* R (97) X = electron-withdrawing or electron-donating group E P PPh2 Ph2P (99) (98) Me N O O O O MeO OMe Me2N C P Mes Ph i NMe 2 Pr 2N (100) Mes P C B C Mes NPri 2 P Pr i2N (101) Mes O Pr i2N O P Mes B C S O (103) i NPr 2 Dipp Dip p N N P P N N Dip p Dip p (104) NPr i2 (102) BH 3 Mes B BH 3 PMe2 Me2P (105) Phosphorus-element bond formation via dehydrocoupling reactions has continued to attract considerable interest, with particular reference to catalytic processes.
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An Introduction to Atomic and Molecular Physics by Wolfgang Demtröder